Deffinely many matches out there:
Reading 5-7 Arsenal (Best match of history) Capital One Cup
Chelsea 6-0 Arsenal & Chelsea 3-5 Arsenal (Both great matches) Premier League
Chelsea 4-4 Liverpool (That's for sure) Champions League
Germany 0-2 Italy (Great late show by Italian stars,Caressa Show) World Cup 2006.
Liverpool 5-4 Alaves (Simply great match) UEFA Cup 2001.
France 1-1 Brazil (Roberto Carlos's curve shot,incredible game) Le Tournoi 1997.
Liverpool 4-3 Newcastle (Last minute goal by Collymore) Premier League
France 0-1 Senegal (Cold shocker for French team) World Cup 2002.
Netherlands 0-1 Spain (Iniesta's last minute goal for World Cup Trophy) World Cup 2010.
Manchester United 2-1 Arsenal (Great match,had everything) FA Cup
Netherlands 2-1 Argentina (Bergkamp's stunning last-minute goal) World Cup 1998.
Arsenal 2-1 Barcelona (Crazy match,best perfomance of both teams) Champions League
There are also other great old matches (Etc. Brazil 0-2 Uruguay,Benfica 2-5 Santos).But it's hard to find highlights of them.
Germany 0-2 Italy, Chelsea 6-0 Arsenal, Brazil 2-1 England (2002 WC), Real Madrid 2-6 Barcelona, Chelsea 4-4 Liverpool, Chelsea 3-5 Arsenal, Spain 4-0 Italy ets etc
Suggest your favorites also